摘要
在碱性条件下,采用水热晶化法,以水玻璃为硅源,表面活性剂十六烷基三甲基溴化铵为结构模板剂,成功合成出全硅MCM-41中孔分子筛。采用X射线衍射分析研究了合成条件(pH值)、凝胶配比(表面活性剂/SiO2、H2O/SiO2)和凝胶后处理条件(老化时间、晶化温度、晶化时间和焙烧温度)对MCM-41结构的影响, 结果表明全硅MCM-41的合成条件为pH 10.5~12.5,表面活性剂/SiO2 0.05~0.7,H2O/SiO2 40~200,老化时间长对合成晶形较好的全硅MCM-41有利,晶化温度70℃~100℃,晶化时间24小时,焙烧温度540℃~740℃。
Under the alkaline condition, the synthesis of mesoporous molecular sieves MCM-41 had been accomplished successfully in a hydrothermal system using sodium silicate as the source of silicon and surfactant C16H33(CH3)3NBr as structural template. The technique of X-ray diffraction was used to identify the effects of the synthesis pH condition, the composition of gel (surfactant/SiO2, H2O/SiO2) and treating conditions of gel (aging time, crystallizing temperature, crystallizing time, calcined temperature) on the crystal structure of MCM-41. The results show that the synthesis conditions for getting suitable mesoporous molecular sieves MCM-41 are pH=10.5-12.5, surfactant/SiO2=0.05-0.7, H2O/SiO2=40-200, aging time as long as possible, crystallizing temperature 70°C-100°C, crystallizing time 24 hours and calcined temperature 540°C-740°C.
出处
《高校化学工程学报》
EI
CAS
CSCD
北大核心
2001年第1期29-34,共6页
Journal of Chemical Engineering of Chinese Universities
关键词
MCM-41中孔分子筛
合成
X射线衍射
水热晶化法
催化剂载体
Crystal structure
Silica
Silica gel
Sodium silicate process
Structural frames
Surface active agents
X ray diffraction