聚合物-纳米无机粒子复合微球研究新进展

Latest Progress in Research of Polymer-Inorganic Nanoparticles Composite Microspheres

近年来,聚合物-纳米无机粒子复合微球相关的设计、制备、以及应用研究得到了科学界众多学者的广泛关注与探索。本文论述了单体聚合法制备聚合物-纳米无机粒子复合微球的研究近况,主要介绍了悬浮聚合、乳液聚合(微乳液聚合、Pickering乳液聚合、细乳液聚合、反相乳液聚合、无皂乳液聚合)、分散聚合及溶液聚合的制备方法。概述了聚合物-纳米无机粒子复合微球在生物医药、光电材料、保护涂层、催化等方面的应用,展望了聚合物-纳米无机粒子复合微球的发展趋势。

In recent years, the design, preparation and application progress of polymer-inorganic nanoparticles composite microspheres have attracted many scholars＇ widely attention and deep exploration. Preparation of poly- mer-inorganic nanoparticles composite microspheres via monomer polymerization methods was reviewed, including suspension polymerization, emulsion polymerization （microemulsion polymerization, pickering emulsion polymeriza- tion, miniemulsion polymerization, reverse emulsion polymerization, soapless emulsion polymerization）, dispersion polymerization and solution polymerization. The applications of these materials in the fields of biological medicine, optoelectronic materials, protective coating and catalyst were ganic nanoparticles composite microspheres were prospected described. Finally, the future trends of polymer-inor-ganic nanoparticles composite microspheres were prospected.