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新型PVC用液体钙锌复合热稳定剂的合成与应用 被引量:3

Study on Synthesis and Application of Ca/Zn Liquid compoend PVC Heat Stabilizer
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摘要 对环氧油酸钙、锌皂的合成工艺,以及聚氯乙烯(PVC)用钙锌复合液体热稳定剂的配方进行研究,并探究了复合热稳定剂的协同效应。通过刚果红法、热老化烘箱法等,考察了钙/锌比、金属皂含量、亚磷酸酯、β-二酮、抗氧剂等对复合热稳定剂热稳定性能的影响,确定了这种液体复合热稳定剂配方。目前两种液体钙锌复合热稳定剂已经中试。 Abstract:The synthetic technology of calcium and zinc epoxy oleates and the formula of zinc-based poly (vinyl chloride) (PVC) compound heat stabilizer were studied.The effects of Ca/Zn ratio,metal soap content,phosphite,β-diketone and antioxidant agent on the thermal stability of the compound heat stabilty were tested through Congo red method,thermal ageing oven method and so on.And two liquid zinc PVC compound heat stabilizers have been produce by pilot-plant.
出处 《塑料助剂》 2014年第2期26-32,共7页 Plastics Additives
关键词 聚氯乙烯 复合稳定剂 液体 环氧油酸钙 合成 应用 poly(vinyl chloride) compound heat stabilizer liquid calcium/Zink epoxy oleate synthesis application
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  • 1Magdy W S, Riham R M, Ahmady A Y. Organic Ther- mal Stabilizers for Rigid Poly (vinyl chloride ) VIII. Phenylurea and Phenyhhiourea Derivatives [ J ]. Poly- mer Degradation and Stability. 2003, (81) :37 -45.
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  • 3Alfredo R, Ma. L B, Norman S A. Synthesis of Dibutyl Tin Di [ (3 -thiopropyl) Trimethoxysilane and its E- valuation as Thermal Stabilizer for PVC [ J ]. Polymer Degradation and Stability, 1999, (63) :359- 363.
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  • 5GB/T2917.1-2002以氯乙烯均聚和共聚物为主的共混物及制品在高温时放出氯化氢和任何其他酸性产物的测定:刚果红法[S].

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