Paleo-redox conditions across the Permian-Triassic boundary in shallow carbonate platform of the Nanpanjiang Basin, South China

Ocean anoxia has been widely implicated in the Permian-Triassic extinction. However, the duration and distribution of the ocean anoxia remains controversial. In this study, the detailed redox changes across the Permian-Triassic boundary （PTB） in the shallow platform interior at Great Bank of Guizhou （GBG） has been reconstructed based on the high-resolution microfossil composition and multiple paleo-redox proxies. The shallow platform is characterized by low sulfur （total sulfur （TS） and pyrite sulfur （Spy）） concentrations, low Spy/TOC ratios, and low DOP values before the mass extinction, representing oxic conditions well. Following the mass extinction, the shift of multiple geochemical proxies, including high Spy/TOC ratios and DOP values, indicates dysoxic-anoxic conditions in shallow ocean. Furthermore, we reconstruct the transition of the redox conditions of Nanpanjiang Basin： the intense volcanic eruptions, which release huge COz and SO2 before the mass extinction, provoke the temperature rising and the collapse of terrestrial ecosystem. As a result, the increased weathering influx causes the carbon iso- topic negative excursion and the expansion of the ocean oxygen minimum zone （OMZ）. When the OMZ expanded into the photic zone, the episodic H2S release events enhance the pyrite burial at Dajiang section. Thus, intense volcanic eruptions, temperature increase, and oceanic hypoxia together lead to the PTB extinction. Recent studies show high temperature might be the key mechanism of the PTB extinction. In addition, this study confirms that the microbialites were formed in the dysoxic- anoxic shallow water.

Ocean anoxia has been widely implicated in the Permian-Triassic extinction.However,the duration and distribution of the ocean anoxia remains controversial.In this study,the detailed redox changes across the Permian-Triassic boundary(PTB)in the shallow platform interior at Great Bank of Guizhou(GBG)has been reconstructed based on the high-resolution microfossil composition and multiple paleo-redox proxies.The shallow platform is characterized by low sulfur(total sulfur(TS)and pyrite sulfur(Spy))concentrations,low Spy/TOC ratios,and low DOP values before the mass extinction,representing oxic conditions well.Following the mass extinction,the shift of multiple geochemical proxies,including high Spy/TOC ratios and DOP values,indicates dysoxic-anoxic conditions in shallow ocean.Furthermore,we reconstruct the transition of the redox conditions of Nanpanjiang Basin:the intense volcanic eruptions,which release huge CO2 and SO2 before the mass extinction,provoke the temperature rising and the collapse of terrestrial ecosystem.As a result,the increased weathering influx causes the carbon isotopic negative excursion and the expansion of the ocean oxygen minimum zone(OMZ).When the OMZ expanded into the photic zone,the episodic H2S release events enhance the pyrite burial at Dajiang section.Thus,intense volcanic eruptions,temperature increase,and oceanic hypoxia together lead to the PTB extinction.Recent studies show high temperature might be the key mechanism of the PTB extinction.In addition,this study confirms that the microbialites were formed in the dysoxicanoxic shallow water.