摘要
Novel porphyrin with carboxy and its zine and iron complexes were synthesized and characterized by MS, EA, IR, UV-vis and 1H NMR. The fluorescence spectroscopic titration of the iron complex to the zinc complex was used to examine their behavior of supramolecular self-assembly and the results indicated that the fluorescence quenche of the zinc complex was resulted from the formation of zinc complex/iron complex supramolecular by hy- drongen-bonding..
Novel porphyrin with carboxy and its zine and iron complexes were synthesized and characterized by MS, EA, IR, UV-vis and 1H NMR. The fluorescence spectroscopic titration of the iron complex to the zinc complex was used to examine their behavior of supramolecular self-assembly and the results indicated that the fluorescence quenche of the zinc complex was resulted from the formation of zinc complex/iron complex supramolecular by hy- drongen-bonding..
出处
《中山大学学报(自然科学版)》
CAS
CSCD
北大核心
2001年第1期125-126,共2页
Acta Scientiarum Naturalium Universitatis Sunyatseni
基金
国家自然科学基金资助项目(29771034
20071034)
广东省自然科学基金资助项目(970152)