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新型羧基卟啉铁(Ⅲ)、锌(Ⅱ)配合物的合成及其超分子自组装 被引量:6

Synthsis and Supramolecular Self-assembly of Novel Zinc and Iron Complexes Prophyrin with Carboxy
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摘要 Novel porphyrin with carboxy and its zine and iron complexes were synthesized and characterized by MS, EA, IR, UV-vis and 1H NMR. The fluorescence spectroscopic titration of the iron complex to the zinc complex was used to examine their behavior of supramolecular self-assembly and the results indicated that the fluorescence quenche of the zinc complex was resulted from the formation of zinc complex/iron complex supramolecular by hy- drongen-bonding.. Novel porphyrin with carboxy and its zine and iron complexes were synthesized and characterized by MS, EA, IR, UV-vis and 1H NMR. The fluorescence spectroscopic titration of the iron complex to the zinc complex was used to examine their behavior of supramolecular self-assembly and the results indicated that the fluorescence quenche of the zinc complex was resulted from the formation of zinc complex/iron complex supramolecular by hy- drongen-bonding..
出处 《中山大学学报(自然科学版)》 CAS CSCD 北大核心 2001年第1期125-126,共2页 Acta Scientiarum Naturalium Universitatis Sunyatseni
基金 国家自然科学基金资助项目(29771034 20071034) 广东省自然科学基金资助项目(970152)
关键词 锌卟啉 铁卟啉 合成 超分子自组装 荧光光谱滴定 羧基卟啉 酰胺键 电子转移 zinc porphyrin iron porphyrin synthesis supramolecular self-assembly fluorescence spectroscopic titration
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