摘要
通过中频非平衡磁控溅射Ti80Si20复合靶在氩气和甲烷混合气氛中沉积Ti-Si-C复合薄膜。采用X射线衍射仪、Raman光谱和X射线光电子能谱分析薄膜微结构。结果显示:制备的薄膜为非晶碳(a-C:Si:H)包裹约10 nm TiC晶粒的复合结构,氩离子溅射刻蚀对XPS分析结果有显著影响。随氩离子刻蚀溅射刻蚀时间增加,薄膜表面C、O原子含量明显降低,而Ti、Si原子含量增加。氩离子溅射刻蚀导致薄膜非晶碳相发生石墨化转变,即sp3C-C(H)/sp2C-C比率减小,同时,C-Ti*/C-Ti和C-(Ti+Ti*)/C-C强度比明显增加。
The Ti-Si-C nanocomposite film was deposited in gas mixtures of Ar and CH4 by middle frequency unbalanced magnetron sputtering Ti80Si20 composite targets. The microstructure of the film was investigated by X-ray diffraction, Raman spectrum and X-ray photoelectron spectroscopy. The results show that the film exhibits nc-TiC/a-C：Si：H nanocomposite structure with about 10 nm nanocrystallites TiC embedded in hydrocarbon （a-C：Si：H） matrix. The results of XPS analysis strongly depend on Ar~ sputter-etching. The C and O content on the film surface distinctly decreases, while the Ti and Si content gradually increase with the increasing of Ar＋ sputter-etching time. It is found that Ar＋ sputter-etching results in the graphitization of the amorphous carbon phase in the nanocomposite film. In other words, the sp3C-C（H）/sp2C-C ratio decreases with the increasing of Ar＋ sputter-etching time. In addition, the C-Ti＊/C-Ti and C-（Ti＋Ti＊）/C-C ratios obviously increase.
出处
《稀有金属材料与工程》
SCIE
EI
CAS
CSCD
北大核心
2014年第4期977-981,共5页
Rare Metal Materials and Engineering
基金
国家自然科学基金资助(5110586)
