以邻菲罗啉为辅助配体的一维Cu(Ⅱ)配合物结构及磁性表征

Synthesis and magnetic properties of one demensional Cu( Ⅱ) complexes with phenanthroline as auxiliary ligands

采用水热法合成了以叠氮钠和邻菲罗啉为配体的一维链状Cu(Ⅱ)配合物,并通过元素分析、红外光谱、X射线单晶衍射和变温磁化率等技术对配合物进行了表征.该配合物属于三斜晶系,P1空间群,a=1.036 4(2),b=1.199 3(2),c=1.548 1(3)nm,α=87.70(3)°,β=84.58(3)°,γ=79.38(3)°,Z=1,V=1.882 3(7)nm3,d=1.735 mg/m3,F(000)=900.对该配合物的磁学性质进行了讨论.

A novel one - dimensional Cu （ Ⅱ ） complex has been synthesized with sodium azide and phenan- throline as ligands by hydrothermal method and characterized by IR spectroscopy, elemental analyses, X - ray crystallography and magnetic susceptibility in this paper. The single crystal of this complex belongs to the triclinic space group P-1 with α=1.0364（2）,b=1.1993（2）,c=1.5481（3）nm,α=87.70（3）°,β=84.58（3）°,γ=79.38（3）°,Z=1,V=1.8823（7）nm3,d=1.735mg/m3,F（000）=900. Magnetic properties of this complex has been discussed.