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新型配合物[ZnBIX(CNAC)_2]_n·nH_2O的合成、结构表征及性质研究

Synthesis,structural characterization and properties of the complex [ZnBIX(CNAC)_2]_n·nH_2O
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摘要 本文利用常规方法合成了[ZnBIX(CNAC)2]n·nH2O,(BIX为1,4-(二亚甲基苯)二咪唑(CNAC为肉桂酸)。并通过元素分析,热重分析,荧光分析和X-射线单晶衍射仪对其进行结构表征。该化合物属于三斜晶系,空间群为P-1,a=10.228(2)魡,b=10.831(2)魡,c=13.416(3)魡,α=84.972(4)°,β=86.295(3)°,γ=77.499(4)°,V=1443.8(5)魡3,C32H30N4O5Zn,Mr=615.97,Dc=1.417g·cm-3,F(000)=640,Z=2,R1=0.0443,wR2=0.0984。 An interest compound [Zn （BIX）（CNAC）n （H2O）] （BIX=1-（4-（（1H-imidazol-1-yl）methyl） benzyl）-1H-imidazole）, CANC=Cinnamic acid） is synthesized by using conventional method and structurally characterized by elemental analysis, thermogravimetric analysis, IR specatrum, and single-crystal X-ray diffraction. Compound crystallizes in the triclinic system, space group P-l, with A=10.228（2）A, b=10.831（2）A, c=13.416（3） A. α=84.972（4）°, fl=86.295 （3）°, γ=77.499（4）°, V=1443.8（5）A3, C32H30N4O5Zn, Mr=615.97,Dc=1.417g·cm^-3,F （000）=640, Z=2, the final R=0.0443 and wR=0.0984. The compound 1 has a 1D S-type chain structure, and generates an infinit 2-D layer with intermolecular hydrogen bonds.
作者 李佳 李惠茹 庄茜 刘春玲 李传碧
机构地区 吉林师范大学化学学院 环境友好材料制备与应用教育部重点实验室
出处 《化学工程师》 CAS 2014年第4期7-10,共4页 Chemical Engineer
基金 四平市科技局项目(No.2012032)
关键词 晶体结构 荧光 热重 crystal structure, photoluminesecent, thermogravimetry
分类号 O625 [理学—有机化学]
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化学工程师
2014年 第4期

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