蔗糖脱水制备5-羟甲基糠醛的研究

Preparation of 5-Hydroxymethylfurfural by Dehydration of Sucrose

研究了Brnsted-Lewis复合催化体系催化蔗糖脱水制备5-羟甲基糠醛,考察了反应条件对5-羟甲基糠醛收率的影响,最佳反应条件为:蔗糖2.0 g,复合催化体系HCl-CrCl3(质量比5∶1)0.8 g,二甲基亚砜20 mL,反应时间30 min,反应温度200℃。在上述较佳反应条件下,蔗糖转化率为100%,5-羟甲基糠醛的收率达72.7%。此外,CrCl3对产物5-羟甲基糠醛具有良好的稳定性,在一定程度上可避免产物继续发生水合/脱羧反应而生成甲酸和乙酰丙酸。

The preparation of 5-hydroxymethylfurfural （ HMF ） from sucrose was studied in the presence of Br nsted-Lewis composite catalytic system. The effects of reaction conditions on the yield of 5-hydroxymethylfurfural were examined. The optimal reaction conditions were obtained as follows： sucrose 2. 0 g, composite catalytic system HCl-CrCl3（mass ratio 5：1） 0. 8 g , dimethyl sulfoxide 20 mL, reaction time 30 min and reaction temperature 200 ℃. Under the above conditions, the conversion of sucrose was 100 %, and the yield of 5-hydroxymethylfurfural reached 72. 7 %. Moreover, CrCl3 had a good stability on the product 5-hydroxymethylfurfural. It could avoid 5-hydroxymethylfurfural over-reacting to form formic acid and levulinic acid by the hydration/decarboxylation reaction to a certain extent.