八甲硫基四氮杂金属卟啉轴向配位研究

Research of Axial Coordination of Octakis( methylthio) porphyrazine Metal Complexes

以顺式-1,2-二氰基-1,2-乙二硫钠盐为原料,与碘甲烷反应生成前驱体二甲硫基马来二腈,以"镁模板法"合成八甲硫基四氮杂金属卟啉,分别通过1H NMR以及GC-MS和Maldi-TOF手段对各产物进行了表征。并且以各种八甲硫基四氮杂金属卟啉为研究对象,摸索了各八甲硫基四氮杂金属卟啉与吡啶的最佳轴向配比。

1,2-bis（ methylthio） maleonitrile was synthesized from disodium salt of dithiomaleonitrile. Then octakis（ methylthio） porphyrazine metal complexes were synthesized by magnesium template reaction method. All complex were characterized by1H NMR,GC-MS,and Maldi-TOF. The most proper axial ligand proportion with pyridine was researched based on metal porphyrazines.