摘要
A novel [2＋4＋2]-macrocyclic compound 3（C52H69N16O12, Mr = 1109.53） con- taining bis（ethoxycarbonyl）glycoluril groups was synthesized via the Mannich three-component reaction in one pot and its structure was characterized by single-crystal X-ray diffraction. It crystallizes in triclinic, space group P1 with a = 10.077（3）, b = 10.642（3）, c = 15.324（5） , α = 96.704（5）, β = 102.304（5）, γ = 104.546（5）°, Z = 2, V = 1528.7（8）3, Dc = 1.283 g/cm3, μ = 0.097 mm-1, F（000） = 628, R = 0.0818 and wR（I 〉 2σ（I）） = 0.2346 for 3034 observed reflections.
A novel [2＋4＋2]-macrocyclic compound 3（C52H69N16O12, Mr = 1109.53） con- taining bis（ethoxycarbonyl）glycoluril groups was synthesized via the Mannich three-component reaction in one pot and its structure was characterized by single-crystal X-ray diffraction. It crystallizes in triclinic, space group P1 with a = 10.077（3）, b = 10.642（3）, c = 15.324（5） , α = 96.704（5）, β = 102.304（5）, γ = 104.546（5）°, Z = 2, V = 1528.7（8）3, Dc = 1.283 g/cm3, μ = 0.097 mm-1, F（000） = 628, R = 0.0818 and wR（I 〉 2σ（I）） = 0.2346 for 3034 observed reflections.
基金
supported by Central China Normal University and the National Science Foundation of China(No.21272085)
