期刊文献+

氯化苄双羰化反应催化剂的研究

Study on the Double Carbonylation Catalyst of Benzyl Chloride
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摘要 Recovery of Co 2(CO) 8 catalyst for the double carbonylation of benzyl chloride was studied. Co 2 (CO) 8 catalyst was recycled four times and the yield of product did not decrease. CoCl 2/Na 2S was used as the double carbonylation catalyst precursor to replace Co 2(CO) 8, and a product yield of 51.5% can be obtained. Recovery of Co 2(CO) 8 catalyst for the double carbonylation of benzyl chloride was studied. Co 2 (CO) 8 catalyst was recycled four times and the yield of product did not decrease. CoCl 2/Na 2S was used as the double carbonylation catalyst precursor to replace Co 2(CO) 8, and a product yield of 51.5% can be obtained.
出处 《分子催化》 EI CAS CSCD 北大核心 2001年第1期69-71,共3页 Journal of Molecular Catalysis(China)
关键词 氯化苄 苯丙酮酸 八羰基二钴 氯化钴 硫化钠 双羰化反应 催化剂 Co 2(CO) 8 CoCl 2/Na 2S Benzyl chloride Phenyl pyruvic acid Double carbonylation
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参考文献3

  • 1[1]Moustafa El-Chahawi, Torisdorf. Method for Preparation of Arylpyruric Acid[P]. US patent, 4 447 664. 1984
  • 2[2]Monflier E, Mortreux A, Petit F. A Convenient Synthesis of Benyl Pyruvic Acid:the Double Carbonylation of Phenylethyl Bromide[J]. Appl Catal, 1993, 102:53~67
  • 3[3]Collin J. Double Carbonylation Reactions: a Review[J]. Bull Soc Chim Fr, 1988, 6:976~981

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