摘要
采用电化学方法在导电基体玻碳 ( GC)电极上制备了二茂铁 ( Fc) -磷钼酸( PMo12 )电荷转移配合物修饰电极 ( Fc5PMo12 /GC)。研究了该电极的电化学行为 ,发现其在硫酸溶液中进行伏安扫描时具有良好的稳定性 ,而且对酸性水溶液中的过氧化氢具有较好的电催化还原作用 。
Ferrocenc dicyclopentadienyl molybdophosphoric heterpoly acid charge transfer coordination compound film modified glassy carbon electrodes have been prepared by electrochemical deposition and their voltammetric behavior were studied. The modified electrodes had good stability in sulfuric acid and high electrocatalytic activity towards the reduction of hydrogen peroxide in acid aqueous solution. The catalytic process was described.
出处
《分析科学学报》
CAS
CSCD
北大核心
2001年第1期21-24,共4页
Journal of Analytical Science
基金
湖北大学人才基金
关键词
二茂铁-磷钼酸电荷转移配合物
过氧化氢
化学修饰电极
电催化还原
制备
Ferrocenc dicyclopentadienyl molybdophosphoric heterpoly acid change transfer coordination compound
Hydrogen peroxide
Chemistry modified electrodes
Electrocatalytic reduction
