摘要
合成了N-正丁基吡啶氟硼酸盐离子液体(BPyBF4)。首次研究了离子液体作为催化剂对标题化合物(AGE)的合成性能。对各因素进行了正交试验分析,结果表明,BPyBF4能较好的催化合成标题化合物,产率60.35%。其结构经过了红外光谱(IR)和氢核磁共振波谱(1HNMR)的验证。
N-Butyl pyridine tetrai]uorohorate ionic liquid （ BPyBF4 ） was successfully synthesized. Ionic liquid as catalyst was investigated for the first time for allyl glycidyl ether （AGE）. Analyzing various factors in the orthogonal experiment,the results show that BPyBF4 can catalytic synthesis of allyl glyeidyl ether well,the yield was 60. 35%. The structure of allyl glycidyl ether was confirmed via infrared spectra （IR） and nuclear magnetic resonance hydrogen spectrum （ ^1HNMR）.
出处
《化学试剂》
CAS
CSCD
北大核心
2014年第6期500-502,565,共4页
Chemical Reagents
关键词
离子液体
烯丙基缩水甘油醚
正交实验
合成
ionic liquid
allyl glyeidyl ether
orthogonal experiment
synthesis
