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聚甲醛的热稳定化研究进展 被引量:3

Research Progress in Thermal Stabilization of Polyoxymethylene
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摘要 聚甲醛由于其特殊的结构导致热稳定性较差,在加工前要进行必要的热稳定化处理。从分子结构着手主要有封端法和熔融后处理法,从体系组成着手可添加抗氧剂、甲醛吸收剂和甲酸吸收剂共同组成一个热稳定体系。综述了聚甲醛热稳定化处理的主要方法,并对各种方法的优缺点进行了对比分析。 In the view of poor thermal stability of polyoxymethylene induced by special structure, thermal stability treatment should be made before processing. From the point of molecular structure, end-blocking and melting processing methods could be utilized. From system composition, antioxidant, formaldehyde absorbents and formic acid absorbent were added together to form a thermal stability system. The main methods of thermal stability of polyoxymethylene were reviewed, and the advantages and disadvantages of various methods were compared and analyzed.
出处 《塑料科技》 CAS 北大核心 2014年第6期113-116,共4页 Plastics Science and Technology
基金 湖北省教育厅产学研重大项目(CXY2009A010) 湖北省自然基金重点项目(2010CDA020) 科技部中小企业创业基金(12C26214204453)
关键词 聚甲醛 热稳定性 封端 稳定剂 Polyoxymethylene Thermal stability End-blocking Stabilizer
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  • 1王俊,杨洪军,李翠勤.受阻酚类抗氧剂的研究进展[J].化学与生物工程,2005,22(8):10-12. 被引量:47
  • 2孙天举,叶林,赵晓文.胺处理聚甲醛的热稳定化研究[J].塑料工业,2006,34(6):50-53. 被引量:5
  • 3HURong-zu SHIQi-zhen.热分析动力学 (Thermal analysis of kinetics)[M].北京:科学出版社 (Beijing: Scientific Press),2001.19.
  • 4Lester P J Burton, Baton Rouge. Phenolic Ester Synthesis: US, 4659863 [P]. 1987-04-21.
  • 5A A Volod'kin, G E Zaikov. Potassium and sodium 2,6-di-tert-butylphenoxides and their properties. Russian Chemical Bulletin [J]. International Edition, 2006, 55(12): 2 220-2 225.
  • 6A A Volod'kin, G E Zaikov. Formation and properties of a catalyst based on sodium and potassium hydroxides in the reaction of 2,6-di-tert-butylphenol with methyl acrylate. Russian Chemical Bulletin [J]. International Edition, 2002, 51(12): 2 189-2 195.
  • 7Toru Yamanaka, Tadatoshi Yoshimura, Iwakuni, et al. Process for preparing tetrakis [3-(3,5-dibutyl-4-hydroxypphenyl)-propionyloxymethyl] methane: US, 4547585[P]. 1985-10-15.
  • 8Samuel Evans, Paul Dubs. Process for the preparation of hydroxyphenylpropionic acid esters: US, 5206414[P]. 1993-04-17.
  • 9Eric J Evain, Krishna Raman. Process for the preparation of aryl-substituted propionic acid esters: US, 5264612[P]. 1993-11-23.
  • 10Christoph K, Gipf O. Method for preparing hydroxyphenyl carboxylic acid esters: JP, 6253942 [P]. 1987.

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