摘要
Coordination interaction is itself a very broad area in chemistry,because more than half of the elements in the periodic table are transition metals.Electron transfer and ligand substitution reactions represent the two major classes of reactivity of transition metal complexes for their crucial applications in catalysis,molecular electronics,and medical chemistry.However,most studies in coordination chemistry,including metal-binding free energies and enthal-
Coordination interaction is itself a very broad ar- ea in chemistry, because more than half of the ele- ments in the periodic table are transition metals. E- lectron transfer and ligand substitution reactions re present the two major classes of reactivity of transi- tion metal complexes for their crucial applications in catalysis, molecular electronics,