期刊文献+

丙烯酸酯/苯乙烯改性水性醇酸树脂的结构与性能 被引量:6

Structure and Properties of Styrene /Acrylate Modified Waterborne Alkyd Resin
下载PDF
导出
摘要 采用两步法合成了一系列组分不同的水溶性苯乙烯/丙烯酸酯改性醇酸树脂。采用FTIR、1H-NMR和GPC分别对树脂的结构、组成及相对分子质量进行了表征。测定了由合成树脂制备的清漆的性能,包括漆膜干燥时间、铅笔硬度、附着力、耐水和耐碱性能。结果表明:改性醇酸树脂具有良好的物理机械性能。 A series of styrene/acrylate modified waterborne alkyd resin with different ratio of styrene and acrylate were synthesized via a two-step process. The structure, component and molecular weight of the modified alkyd resins were characterized by FT-IR, 1H-NMR and GPC. A varnish was prepared by diluting the said resin with water and its film performance was determined in terms of drying time, pencil hardness, adhesion, resistance to water and alkaline. The results showed that the styrene/acrylate (molar ratio 1:1.6 ) modified waterborne alkyd resin exhibited excellent physical properties.
出处 《涂料工业》 CAS CSCD 北大核心 2014年第7期46-51,共6页 Paint & Coatings Industry
基金 中国科学院西部之光项目编号:XBBS201117 新疆乌鲁木齐科技局科技攻关项目批准号:k111110002 新疆维吾尔自治区科技计划项目编号:201215142
关键词 水溶性 醇酸树脂 苯乙烯 丙烯酸酯 快干性 硬度 waterborne alkyd resin styrene acrylate fast drying hardness
  • 相关文献

参考文献20

  • 1WEISSENBORN P, MOTIEJAUSKAITE A. Emulsification, drying and film formation of alkyd emulsions[J].Progress in Organic Coatings, 2000. 40(1) : 253-266.
  • 2NABUURS T, BAIJARDS R, GERMAN A. Alkyd-acrylic hybrid systems for use as binders in waterborne paints[ J ]. Progress in Organic Coatings, 1996, 27( 1): 163-172.
  • 3DERISS M, KARLSSON O. Suspension structures and film morphologies of high-solids acrylic-alkyd hybrid binders [ J ]. Surface Coatings International Part B : Coatings Trans- actions, 2005, 88(4): 251-256.
  • 4WANG C, GENG L, JOON H P, e! al. Novel synthesis of carboxy-functional soybean acrylic-alkyd resins for water- reducible coatings [ J 1. Journal of Coatings Technology, 2000, 72(904): 55-61.
  • 5AKBARINEZHAD E, EBRAHIMI M, KASSIRIHA S M, et al. Synthesis and evaluation of water-reducible acrylic- alkyd resins with high hydrolytic stability [ J ]. Progress in Organic Coatings, 2009, 65(2): 217-221.
  • 6SARAVARI O, PHAPANT P, PIMPAN V. Synthesis of water-reducible acrylic- alkyd resins based on modified palm oil[ J ]. Journal of Applied Polymer Science, 2005, 96(4) : 1170-1175.
  • 7HARRIS R R, POLLACK W J. Acrylate-modified alkyd resin : USA, 4133786 [ P ]. 1979-01-09.
  • 8USCHANOV P, HEISKANEN N, MONONEN P, et al. Synthesis and characterization of tall oil fatty acids-based alkyd resins and alkyd-acrylate eopolymers [ J ]. Progress in Organic Coatings, 2008, 63(1) : 92-99.
  • 9刘国杰.醇酸-丙烯酸水性涂料杂化改性研究进展[J].现代涂料与涂装,2010,13(1):28-31. 被引量:13
  • 10克拉克,赫尔墨,朔尔夫.丙烯酸类改性的水性醇酸树脂或氨基甲酸酯改性醇酸树脂分散体:CN,1365368A[P].2002-08-21.

二级参考文献25

  • 1胡乔生,叶家波,范小林,张熊禄.水溶性醇酸树脂涂料的研究进展[J].赣南师范学院学报,2005,26(6):54-57. 被引量:11
  • 2刘峰,王国建,刘琳.水分散性醇酸树脂的研究[J].材料工程,2006,34(4):12-15. 被引量:13
  • 3文艳霞,闫福安.水性醇酸树脂的合成及改性的研究进展[J].上海涂料,2007,45(2):21-25. 被引量:14
  • 4涂料工艺编辑委员会.涂料工艺(下册)[M].第3版.北京:化学工业出版社.1997:330.
  • 5[美]ZenoW.威克斯等著,经桴良,姜英涛等译.虞兆年校.有机涂料科学和技术[M].北京:化学工业出版社.2002:311.
  • 6Umesh Sawant & M.V.K.Kannan.Water soluble alkyds:Environmentally friendly formulations[J]. Paintindia, 1998(8):81.
  • 7G. o stbergm, et al. Alkyd emulsions[J]. Prog . in Org. Coat,1994(24):281.
  • 8Jochum Beetsma. Alkyd emulsions paints : properties, challenges and solutions[J].Pigment & Resin Technology,1998,27 (1):12-19.
  • 9M J Deriss, O J Karlsson. Suspension structures and film morphologies of high-solids acrylic-alkyd hybrid binders[J]. Surface Coatings International Part B:Coatings Transactions, 2005,188(B4):231-316.
  • 10E.M.S. Van Hamersveld et al. Oil-acrylie hybrid latexes as binder for water borne coatings [J].Prog.in Org.Coat,1999 (35):235.

共引文献59

同被引文献89

  • 1文艳霞,闫福安.水性醇酸树脂及其聚氨酯改性的研究[J].中国涂料,2007,22(1):25-28. 被引量:14
  • 2孙凌,赵其中,董玉婷.醇酸树脂的转相乳化[J].上海涂料,2007,45(4):9-12. 被引量:5
  • 3周波.豆油脚脂肪酸制备松香改性醇酸树脂的配方研究[J].涂料工业,2007,37(6):58-60. 被引量:2
  • 4陈俊,文风,刘身凯,等.一种环氧改性水性醇酸树脂及其制备方法:中国,101838389[P].2010-09-22.
  • 5HHGEDUS C R, PEPE F R,DICKENSON J B,et al. Waterborne acrylic-epoxy coatings [J]. Journal of Coatings Technology, 2002,74 (927):31-39.
  • 6DUTTA N, KARAK N, DOLUI S K‘ Alkyd-epoxy blends as multipurposecoatings [J]. Journal of Applied Polymer Science, 2006,100 (1): 516-521.
  • 7PATEL H S,PATEL B K, PATEL K B, et a丨.Surface coating studies ofalkyd-castor oil-epoxy resin condensate-ketone resin blends [J].International Journal of Polymeric Materials and Polymeric Biomaterials,、 2009,59(1):25-32.
  • 8华南理工大学.一种环氧丙烯酸酯改性水性醇酸树脂及其制备方法与应用:CN,104086712 [P]. 2014-10-08.
  • 9NIMBALKAR R V,ATHAWALE V D. Synthesis and characterization ofcanola oil alkyd resins based on novel acrylic monomer (ATBS) [J].Journal of the American Oil Chemists’ Society, 2010,87 (8): 947-954.
  • 10DZICZKOWSKI J,SOUCEK M D. A new class of acrylated alkyds [J].Journal of Coatings Technology and Research, 2010, 7 (5): 587-602.

引证文献6

二级引证文献12

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部