摘要
制备了一系列PMN-BT陶瓷,系统地研究了BT含量的变化对介电性能和相变温度的影响.PMN-BT陶瓷的相变温度与组成呈“U”型变化曲线.相变温度的异常变化是由于系统中存在Ba(Mg1/3Nb2/3)O3顺电微区所致.PMN-BT陶瓷的介电弛豫特性随BT的增加经历了一个由弱变强,再由强变弱的过程.对由两种钙钛矿化合物构成的铁电固溶体相变温度的变化规律进行了讨论.
The dielectric properties of PMN-BT solid solution ceramics were systematically studied. The change of the transition temperature with composition is in the form of 'U' curve and the possible cause may be existing of paraelectric phase Ba(Mg1/3Nb2/3)O-3 in PMN-BT ceramics. The effects of composition on dielectric relaxation for PMN-BT ceramics were studied. With increasing BT content, dielectric relaxation of PMN-BT ceramics was increasing first, then decreasing. The characteristics of phase transition temperature of the ferroelectric solution composed of two perovskite compound were also discussed.
出处
《无机材料学报》
SCIE
EI
CAS
CSCD
北大核心
2001年第2期324-330,共7页
Journal of Inorganic Materials
基金
西安交通大学科学研究基金资助!(573017)
关键词
铌镁酸铅
钛酸钡
介电性能
相变温度
铁电体
陶瓷材料
lead magnesium niobate
barium titanate
dielectric properties
transition temperature