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Effect of y/x ratio on luminescence properties of xSrO·yAl_2O_3:Eu^(2+),Dy^(3+) luminous fiber 被引量:8

Effect of y/x ratio on luminescence properties of xSrO·yAl_2O_3:Eu^(2+),Dy^(3+) luminous fiber
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摘要 Rare earth strontium aluminate luminous fiber is a novel functional fiber. In order to investigate the influence of Al/Sr ratio on luminescence properties of xSrO·yAl2O3:Eu2+,Dy3+ luminous fibers, several kinds of rare earth strontium aluminate luminous fibers were prepared by using rare-earth strontium aluminate as the rare-earth luminescent material and fiber-forming polymers such as polymer polyethylene terephthalate(PET) as a matrix and combining them with functional additives. X-ray diffraction(XRD), fluorescence spectrophotometer, and afterglow brightness tester as well as microcomputer thermo-luminescence dosimeters were used to characterize the resulting samples. Results from XRD demonstrated that the phase of xSrO·yAl2O3:Eu2+,Dy3+ luminous fibers were different from one another as the Al/Sr ratio changed. Emission spectra of the samples with different Al/Sr ratios showed that emission intensity increased with the decrease of A1/Sr ratio at first then increased when it was over 2/1. From afterglow decay results, it could be found that Sr-rich sample showed lower luminance and shorter persistent time. Rare earth strontium aluminate luminous fiber is a novel functional fiber. In order to investigate the influence of Al/Sr ratio on luminescence properties of xSrO·yAl2O3:Eu2+,Dy3+ luminous fibers, several kinds of rare earth strontium aluminate luminous fibers were prepared by using rare-earth strontium aluminate as the rare-earth luminescent material and fiber-forming polymers such as polymer polyethylene terephthalate(PET) as a matrix and combining them with functional additives. X-ray diffraction(XRD), fluorescence spectrophotometer, and afterglow brightness tester as well as microcomputer thermo-luminescence dosimeters were used to characterize the resulting samples. Results from XRD demonstrated that the phase of xSrO·yAl2O3:Eu2+,Dy3+ luminous fibers were different from one another as the Al/Sr ratio changed. Emission spectra of the samples with different Al/Sr ratios showed that emission intensity increased with the decrease of A1/Sr ratio at first then increased when it was over 2/1. From afterglow decay results, it could be found that Sr-rich sample showed lower luminance and shorter persistent time.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2014年第7期598-602,共5页 稀土学报(英文版)
基金 Project supported by National Natural Science Funds(21171074/B010201) National High-Tech R&D Program of China(863 Program)(2012AA030313)
关键词 rare earth luminous fiber xSrO·yAl2O3:Eu2+ Dy3+ emission spectra rare earth luminous fiber xSrO·yAl2O3:Eu2+ ,Dy3+ emission spectra
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