二茂铁甲酰羟胺衍生物及其铜(Ⅱ)螯合物的合成

Synthesis of some Ferrocenoylaryl hydroxylamines and Their Cu (Ⅱ)Chelates

用二茂铁甲酰氯和取代苯胲反应。合成了七种N-二茂铁甲酰基-芳基羟胺,并以这些化合物做为配体,合成了它们的铜(I)蝥合物。通过元素分析,红外光谱,核磁共振氢谱确证了化合物的结构。合成的螯合物有可能用做复合固体推进剂的燃速调节剂。

A series of N-ferrocenoylarylhydroxylamines have been synthesized by the partial acylation of arylhydroxylamines with the ferrocenoyl chloride. These organometallic compounds can act as ligands for metal chelation and their C_u(Ⅱ) chelates have been isolated. The ligands and chelates have been characterized by elemental analysis IR and IHNMR spectra. The chelates are potential solid propellant burning rate modifiers.