摘要
A binuclear silver complex,Ag2Br2(PPh3)3·CH2Cl2,Mr=1247.4,monoclinic P21/c,a=16.306(3).b=18.444(3),c=18.807(3),β=111.21(2)°,V=5274.1(4).,Z=4,Dc=1.575 g/cm3,λ(MoKα)=0.71073,μ(MoKα)=24.7cm(-1),F(000)=2480,final R=0.071,Rw=0.075 for 5007observed reflections.In the complex,Ag(1)and Ag(2)are bridged by two bromineatoms and coordinated in tetrahedral and trigonal geometries,respectively.
A binuclear silver complex,Ag2Br2(PPh3)3·CH2Cl2,Mr=1247.4,monoclinic P21/c,a=16.306(3).b=18.444(3),c=18.807(3),β=111.21(2)°,V=5274.1(4).,Z=4,Dc=1.575 g/cm3,λ(MoKα)=0.71073,μ(MoKα)=24.7cm(-1),F(000)=2480,final R=0.071,Rw=0.075 for 5007observed reflections.In the complex,Ag(1)and Ag(2)are bridged by two bromineatoms and coordinated in tetrahedral and trigonal geometries,respectively.
