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Crystal Structure of μ-[meso-1,2-Bis (n-propylsulphinyl)ethane]-(O,O')-[diphenyltin (Ⅳ) dichloride]

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摘要 The title complex C_(20)H_(28)C;_2O_2S_2Sn is of monoclinic system space group P2_1/a with its cell parameters:a=16.741 (4), b=11.942(4), c=24. 747(3) A, β= 103. 99(1)°, V=4800. 85 A ̄3, Z=8, M_r=554. 17, D_x=1. 533 g/cm ̄3, μ(MoKa)= 14. 7 cm ̄(-1). The structure was refined to an R of 0.054 and R_w of 0. 060 for 3472 unique diffraction data [I≥3σ(I)]. The unique tin atom has a distorted octahedral coordination geometry. The crystal structure shows that there are two independent chains of each other in every asymmetry unit. The title complex C_(20)H_(28)C;_2O_2S_2Sn is of monoclinic system space group P2_1/a with its cell parameters:a=16.741 (4), b=11.942(4), c=24. 747(3) A, β= 103. 99(1)°, V=4800. 85 A ̄3, Z=8, M_r=554. 17, D_x=1. 533 g/cm ̄3, μ(MoKa)= 14. 7 cm ̄(-1). The structure was refined to an R of 0.054 and R_w of 0. 060 for 3472 unique diffraction data [I≥3σ(I)]. The unique tin atom has a distorted octahedral coordination geometry. The crystal structure shows that there are two independent chains of each other in every asymmetry unit.
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 1996年第1期20-23,共4页 结构化学(英文)
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参考文献3

  • 1Zhu F C,Inorg Chim Acta,1990年,171卷,85页
  • 2邵晶西,Chem J Chin Univ,1989年,10卷,821页
  • 3Zhang R H,J Chin Rare Earth Soc,1987年,5卷,7期

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