摘要
Cu(S_2CNC_5H_10)_2], Mr= 384. 17, monoclinic, space group P2_1/c,a =6.162(2), b=8. 566(3), c=15. 257(4), β=95. 57(2)￣°, V=801. 5, Z=2,D_c = 1. 60g/cm￣3, μ(MoKα) = 18. 6 cm￣-1, F(000)=398, final R= 0. 036 and R_w=0. 039 for 1188 reflections with I≥4.0σ(I). The Cu(Ⅱ) atom displays a nearly square planar coordination geometry with Cu-S bond lengths ranging from 2. 289 ( 3 ) ￣ 2. 307(3).
Cu(S_2CNC_5H_10)_2], Mr= 384. 17, monoclinic, space group P2_1/c,a =6.162(2), b=8. 566(3), c=15. 257(4), β=95. 57(2)￣°, V=801. 5, Z=2,D_c = 1. 60g/cm￣3, μ(MoKα) = 18. 6 cm￣-1, F(000)=398, final R= 0. 036 and R_w=0. 039 for 1188 reflections with I≥4.0σ(I). The Cu(Ⅱ) atom displays a nearly square planar coordination geometry with Cu-S bond lengths ranging from 2. 289 ( 3 ) ￣ 2. 307(3).
