含二茂铁基的酰氧基二-(甲基环戊二烯基)钛衍生物的合成和性能研究

Synthesis and Properties of Ferrocene Acyloxy-bis (methylcyclopentadienyl) titanium Compounds

本文合成了十种新的含二茂铁基的酰氧基二－（甲基环戊二烯基）钛，（η^5-CH3C5H402TiCl2-nYn(Y=二茂铁羧酸基）。进行了元素分析，讨论了它们的紫外和红外光谱，及核磁共振谱。

The ferrocene acyloxy-bis(methylcyclopentadienyl) titanium derivatives, (η~5- CH_3C_5H_4)_2TiCl_(2-n)Y_n, where n-1, Y=FcCOO(1), FcCH_2COO(2), FcCOCH_2COO(3), FeCO(CH_2)_2COO(4), Fc(CH_2)_3COO(5), 3-(ferrocenecarbonyl) bicyclo [2.2.1] hept-5- ene-2-carboxy(6); n=2, Y=FeCOO(7), FeCO(CH_2)_2COO(8), Fe(CH_2)_3COO(9); Y_n= Fe(C_5H_4COCH_2CH_2COO)_2(10); Fe=ferrocenyl, have been synthesized and their IR, NMR and UV spectra are discussed.