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聚酰胺-胺型树枝状化合物与四氯化钛的配合及其催化作用初步研究 被引量:34

PAMAM Dendritic Titanium Tetrachloride Complexes and Their Catalytic Reactivity
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摘要 The modification of PAMAM( G =3 0) dendrimers was achieved by using aldehyde, benzyl chloride and trityl chloride as reaction agents, respectively. The complexes were synthesized simply by dropping TiCl 4 solution into the modified PAMAM dendrimers that were dissolved in certain solvent. The quantity of Ti contained in the complexes increased as the adding amount of TiCl 4 was increased. The polymerization of α methyl styrene catalyzed by the complexes was accomplished and it has shown that the complexes possessed catalytic function. The modification of PAMAM( G =3 0) dendrimers was achieved by using aldehyde, benzyl chloride and trityl chloride as reaction agents, respectively. The complexes were synthesized simply by dropping TiCl 4 solution into the modified PAMAM dendrimers that were dissolved in certain solvent. The quantity of Ti contained in the complexes increased as the adding amount of TiCl 4 was increased. The polymerization of α methyl styrene catalyzed by the complexes was accomplished and it has shown that the complexes possessed catalytic function.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2001年第4期709-711,共3页 Chemical Journal of Chinese Universities
基金 国家自然科学基金! (批准号 :5 9673 0 10 )资助
关键词 树枝状化合物 四氯化钛 聚酰胺 配合物 催化作用 催化剂 Dendrimer Complex Titanium tetrachloride α Methyl styrene
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