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Structure of 〔Pyridine(tris(2-aminothylamine〕copper(Ⅱ) Diperchlorate 〔Cu(C_6H_(18)N_4)(C_5H_5N)〕(ClO_4)_2

Structure of 〔Pyridine(tris(2-aminothylamine〕copper(Ⅱ) Diperchlorate 〔Cu(C_6H_(18)N_4)(C_5H_5N)〕(ClO_4)_2
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摘要 The title complex, tpyridine (tris (2-aminothylamine] copper (Ⅱ)diperchlorate, [Cu(C6H18N4) (C5H5N)] (ClO4),, crystallizes in the orthorhombic spacegroup Pnma with independent reflections with F>4(F). The coordination geometry about the copper(Ⅱ) atom is a trigonal bipyramid with geometry parameter value of 0. 94. The cation has C, symmetry with the mirrorplane at Y=1/4. The title complex, tpyridine (tris (2-aminothylamine] copper (Ⅱ)diperchlorate, [Cu(C6H18N4) (C5H5N)] (ClO4),, crystallizes in the orthorhombic spacegroup Pnma with independent reflections with F>4(F). The coordination geometry about the copper(Ⅱ) atom is a trigonal bipyramid with geometry parameter value of 0. 94. The cation has C, symmetry with the mirrorplane at Y=1/4.
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 1998年第2期94-96,共3页 结构化学(英文)
关键词 copper(Ⅱ) complex crystal structure tripodal complex copper(Ⅱ) complex, crystal structure, tripodal complex
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参考文献3

  • 1Lu Z L,Inorg Chem,1996年,35卷,2253页
  • 2Gou S H,Inorg Chem,1993年,32卷,1883页
  • 3Addison A W,J Chem Soc Dalton Trans,1984年,1349页

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