摘要
The compound [Fe2V(μ3-O) (μ-O2CCH3), (THF)3]Cl. 3H2O (THF=tetrahydrofuran) crystallizes in monoclinic system, space group C2, with cell di-mensions a= l2. 847(2), b= l5. 875 (6), c= lO. 211 (3) A, β= 109- 34 (3)', V=1965. 1(4) A3, Z= 2, D,c= 1. 73 g/cm'3 Mr= 838. 5 . F(000) = 1040, λ(MoKa) =14. 0 cm-1. The final R=0. 094, Rw= 0. O95 for 13O4 observed reflections with I≥3. 0σ (I). The result of structure analysis indicates that the framework of this com-pound is a typical trimeric oxo ccntered carboxylato compound.
The compound [Fe2V(μ3-O) (μ-O2CCH3), (THF)3]Cl. 3H2O (THF=tetrahydrofuran) crystallizes in monoclinic system, space group C2, with cell di-mensions a= l2. 847(2), b= l5. 875 (6), c= lO. 211 (3) A, β= 109- 34 (3)', V=1965. 1(4) A3, Z= 2, D,c= 1. 73 g/cm'3 Mr= 838. 5 . F(000) = 1040, λ(MoKa) =14. 0 cm-1. The final R=0. 094, Rw= 0. O95 for 13O4 observed reflections with I≥3. 0σ (I). The result of structure analysis indicates that the framework of this com-pound is a typical trimeric oxo ccntered carboxylato compound.
