摘要
The crystal of the title complex with formula C48H52N8O16CI2Cd3(Mr=1405. 10) was crystallized in monoclinic, space group P21/n, with a=12. 666 (3), b=18. 306(6), c=13. 231 (4) A, p=111. 68(3), V=2851 (2) A3, Z=2, Dr=1. 637 g/cm-3 p=12. 680 cm-1, F(000)=1404. The final refinement is convergedwith R=0. 052 and Rw=0. 055. In the molecule [Cd3(py8(Oac)4] (CIO4)2, the aver-age values of Cd-N and Cd-O bonds are 2. 306 and 2. 288 A, respectively. In thecanon of the title complex. each Cd atom is coordinated by N and O atoms, which arefrom pyridine molecules and acetatoes, respectively, to form a distorted octahedron.And three Cd atoms are linked by two u2-O atoms of two acetatoes and other two u-ac-etato side bridges.
The crystal of the title complex with formula C48H52N8O16CI2Cd3(Mr=1405. 10) was crystallized in monoclinic, space group P21/n, with a=12. 666 (3), b=18. 306(6), c=13. 231 (4) A, p=111. 68(3), V=2851 (2) A3, Z=2, Dr=1. 637 g/cm-3 p=12. 680 cm-1, F(000)=1404. The final refinement is convergedwith R=0. 052 and Rw=0. 055. In the molecule [Cd3(py8(Oac)4] (CIO4)2, the aver-age values of Cd-N and Cd-O bonds are 2. 306 and 2. 288 A, respectively. In thecanon of the title complex. each Cd atom is coordinated by N and O atoms, which arefrom pyridine molecules and acetatoes, respectively, to form a distorted octahedron.And three Cd atoms are linked by two u2-O atoms of two acetatoes and other two u-ac-etato side bridges.
