摘要
The reaction of Ru(DMSO)4Cl2 and Ph2PN (i-Bu)Ph2(1:2) gave the title compound, trans-RuCPh2PN(i-Bu)PPh2]2Cl2. Crystallographic data for C56 H58Cl2N2P4Ru: triclinic, space group P1, a = 11. 575(1), b = 12. 193(3), c = 20. 297(4)A, α=75. 30(2),β=76.28(1),γ= 72. 08(2)°, V = 2596. 6(8)A3, Z = 2, Mr = 1054. 97, Dc=1. 35g/cm3,μ(MoKa) = 5. 58cm-1, F (000) = 1092; R = 0. 046 and Rw = 0. 056 for 3411 observed reflections. The Ru atom is coordinated by four P atoms and two Cl atoms, forming an octahedral configuration.
The reaction of Ru(DMSO)4Cl2 and Ph2PN (i-Bu)Ph2(1:2) gave the title compound, trans-RuCPh2PN(i-Bu)PPh2]2Cl2. Crystallographic data for C56 H58Cl2N2P4Ru: triclinic, space group P1, a = 11. 575(1), b = 12. 193(3), c = 20. 297(4)A, α=75. 30(2),β=76.28(1),γ= 72. 08(2)°, V = 2596. 6(8)A3, Z = 2, Mr = 1054. 97, Dc=1. 35g/cm3,μ(MoKa) = 5. 58cm-1, F (000) = 1092; R = 0. 046 and Rw = 0. 056 for 3411 observed reflections. The Ru atom is coordinated by four P atoms and two Cl atoms, forming an octahedral configuration.
