摘要
众多文献认为,不能用电负性来解释同族氢酸酸强的变化规律。本文给出一个以电负性等参数与氢酸酸强pka关系的经验公式,满意地解释了同族及同周期氢酸酸强的变化规律。
Many authors showed that the trend of the strength of hydroacids of the elements within main group is not explained with the electronegativity. In this article, we give an empirical equation to relate the strength of hydroacids,pka,with the electronegativity,covelcnt readius,and absolute value of the oxidation number of the element. It can explain satisfactorily the trend of the strength of hydrocids.
出处
《安徽大学学报（自然科学版）》
CAS
1990年第1期58-61,共4页
Journal of Anhui University(Natural Science Edition)
关键词
酸强度
电负性
共价半径
氧化数
氢酸
量度
acid strength (pka)
electronegativity
covelentradius
oxidation number
