芳香胺氮氧化物合贵金属配合物研究 Ⅱ、1,10-菲啰啉-N-氧化物与金(Ⅲ)、铂(Ⅳ)和钯(Ⅱ)的配合物的合成与表征

Studies on the Noble Metal Complexes With Aromatic Amine N-Oxide Ⅱ Synthesis and Characterization of Gold (Ⅲ) , Platinum (Ⅳ) and Palladium (Ⅱ) Complexes With 1,10-Phenanthroline-N-Oxide

合成金(Ⅲ)、铂(Ⅳ)、钯(Ⅱ)与1,10-菲啰啉-N-氧化物的三种固体配合物,用元素分析、摩尔电导、红外和紫外光谱、差热分析和荧光光谱对配合物的组成和性质进行了研究,并讨论了配合物的可能结构,配合物中均含有[H(PhenO)]^+大阳离子,在结构上具有氢键的特征.

The title complexes have been synthesized and characterized by elemental analyses, molar conductance, DTA, IR, UV and fluorescence spectra. The possible structure of complexes has been discussed too. The complexes have been supposed to be ion-associated complexes with hydrogen bond.