ADM法在配合物空间构型讨论中的应用

Application of ADM method in complex space configuration

利用角重叠模型法 ( ADM法 )对具体的 7种常见配合物的空间构型进行了讨论与分析 ,通过各种构型的结构选择能的理论计算 ,排出了各种构型的选择顺序和各配合物的预测构型 .预测构型与实际构型十分吻合 ,从而通过理论计算总结出了一种较为理想的确定配合物构型的理论方法 .

The space configuration of seven kinds of common complex were studied by using model of overlapping angles.The selecting order of various configurations and intended configuration of complexes were given by the theoretical calculation of selecting energy of configuration.The intended configurations consist with the practical ones.A theoretical method for pre defining complex configuration was put forward.