氯化聚丙烯(PPCl)聚吡咯(PPy)共混体系的研究(1)—PPCl-PPy共混物的制备及导电性

STUDIES ON CHLORINATED POLYPROPYLENE (PPCl)- POLYPYRROLE (PPy) BLEND SYSTEM I. PREPARATION AND CONDUCTIVITY

本文通过一种新的方法合成了PPCl-PPy导电材料,并对合成反应的各种影响因素及材料的导电性作了详细探讨。结果表明,本文采用的PPCl-FeCl_3共混体系具有良好的成形性能,所合成的PPCl-PPy导电材料在低聚吡咯含量时可达到高电导率,而且对热及大气具有良好的稳定性。

A new PPCI-PPy polyblend conductive material is synthesized by means of a new method for the first time. The effects of various conditions on polymerization and the conductivity of the new material is investigased. It is found that PPCl-FeCl3 composite has excellent film forming ability while PPCl-PPy composite film can attain high conductivity as low content of polypytrole and is stable to heat and atmosphere. : ?