期刊文献+

负载型铁基复合金属氧化物对苯直接羟基化反应催化作用的研究 被引量:4

STUDIES ON SUPPORTED COMPLEX METAL OXIDES CATALYSIS FOR THE HYDROXYLATION OF BENZENE
下载PDF
导出
摘要 对负载型铁基复合金属氧化物对苯羟基化反应的催化作用进行了研究 ,并考察了催化剂及用量、溶剂、进料比、反应温度和反应时间对羟基化反应的影响。 This paper mainly deals with supported complex metal oxides catalysts used in the benzene hydroxylation under mild conditions. The study is focused on these factors including active participants, carriers and other reaction conditions such as the usage of catalyst, the benzene/H 2O 2 molar ratio, the reaction temperature and the time of reaction, etc. The effect of reaction medium and solvent is very important. The addition of solvent helps mixing benzene with hydrogen peroxide. The hydroxylation of benzene is carried out using acetone as solvent. Finally, the process of benzene hydroxylation is proposed.
出处 《化工科技》 CAS 2001年第1期27-30,共4页 Science & Technology in Chemical Industry
基金 燕山石化公司研究院资助
关键词 过氧化氢 羟基化 负载型 铁基复合金属氧化物 反应催化 Benzene Hydrogen peroxide Hydroxylation Complex metal oxides
  • 相关文献

参考文献7

  • 1姚蒙飞.精细化工产品合成原理[M].中国石化出版社,1992.42~73.
  • 2V.I.SoboleV,K.A.Dubkov,E.A.Paukshtis,et al.On the Role of Bronsted Acidity in theOxidation of Benzene to Phenol by Nitrous Oxide[J],Appl.Cata.A:General,1996,141:185~192.
  • 3S.Tamagaki,M.Sasaki,W. Tagaki.Fe(Ⅲ)-catalyzed Aromatic Hydroxylation with H2O2in the Presence of a Variety of Electron-transfer Agents[J],Bull.of Chem.Soc.Jpn.,1989,62:153~158.
  • 4E.A.Karahanov,S.Y.Narin,A.G.Dedov.The Effective Hydroxylation of Benzene byHydrogen Peroxide in a Heterophase System[J],Catal.Lett.,1989,3:31~36.
  • 5J.S.Reddy,R.Kumar.Synthesis,Characterization and Catalytic Properties of a TitaniunSilicata,TS-2,with MEL Structure[J],J Catal.,1991,130:440~446.
  • 6R.Ugo,E.Antonio,M.Federico,et al.selective Oxidation with Titanium silicalite[J].chim.Ind(Milan,Italy),1990,72(7):610~616.
  • 7张信芳,张天巧,萨学理.负载型铁基复合金属氧化物对苯酚羟基化反应催化作用的研究[A]. 98'国际华人石油与石油化工科技研讨会, 北京, 1998:488-491.

共引文献2

同被引文献27

引证文献4

二级引证文献22

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部