摘要
上世纪初发现自由基反应,其特点有三:引发、传递和终止;分为单分子和双分子反应,共振杂化体越多的自由基越稳定,对自由基稳定有利的空间构型其反应易进行,溶剂化作用,氢键的形成,过渡态活化能等对自由基反应都有影响。
Free radical reaction discovered at the beginning of last century has got three features:initiation,transmit and termination; grouped into mono-molecular and bi-molecular reaction. When the free radical of resonant isomerism is more, the free radical is more stable.The space structure beneficial to the free radical stability, free radical reaction is easily going. And solvent action,hydrogen bond formation,transition activation energy all are reaction to free radical.
作者
文耀智
Wen Yaozhi (Department of Chemistry, Chenzhou Teachers College, Chenzhou 423000)$$$$
出处
《邵阳师范高等专科学校学报》
2001年第2期42-48,共7页
Journal of Shaoyang Teachers College