摘要
自从１９７５年Ｗｒｉｇｈｔ等［１］首次发现了ＰＥＯ碱金属盐络合物的离子导电性后，人们对不同类型的聚合物固体电解质进行了深入的研究，其中最成功的是玻璃化温度Ｔｇ较低、盐浓度适中的“ｓａｌｔｉｎｐｏｌｙｍｅｒ”固体电解质［２，３］，但在没有其它小分...
Ionic conductivity of a novel predominantly lithium\|ion\|conducting solid polymer electrolyte is studied. The electrolyte comprises molten lithium salt(s)\|acetamide\|urea mixtures in which a small amount of an poly(ethylene oxide) is dissolved to stabilized it against recrystallization. The electrolyte has exceptionally hight conductivity at temperature of 70 or lower, including ambient temperature, for example 10-3S/cm at 70 and 10-4S/cm at 25. The electrolyte combines the best features of the other two, superionic glass electrolyte and salt\|in\|polymer electrolyte. Its inoic conductivity depends on the low melting\|point eutectic as well as the molecular weight and content of poly(ethylene oxide).\=
出处
《高分子学报》
SCIE
CAS
CSCD
北大核心
1999年第3期373-376,共4页
Acta Polymerica Sinica
