摘要
本文通过模拟经验平衡常数 K 与标准平衡常数 K°,标准吉氏自由能变化△G°,标准焓变△H°及标准熵变△S°等热力学关系,导出了理想溶液反应及理想气体反应的 ACT 热力学表达式.
The article has deduced thermodynamic formulation of ACT of the ideal—solution re- action and the ideal—gas reaction through imitated thermodynamic formulations of experience equilibri- um constant K with standard equilibrium constant K~,standard Gibbs free energy change △G~,stan- dard enthalpy change △H~ and standard entropy change △S~ ect.
关键词
活化络合物理论
热力学
ACT热力学表达式
activated complex theory
thermodynamic
thermodynamic formulation of ACT
