摘要
本文对作者提出的计算直链饱和卤代烃沸点经验公式Tb(℃)=133.54n^(1/2)+123.49r_x^(3/2)-14.292n^(1/2)r_x^(3/2)--279.4进行了分析和探讨。由上式出发,讨论了直链饱和烃的沸点变化规律,计算了氢(H_2)和卤化氢(HX)的沸点,并与实际结果进行了比较,最后对修正项的意义也作了简要讨论。
The empirical formula which was proposed in our previous work to calculate the Boiling Points of 1-Haloalkanes is further analysed and approached in this paper. Based on the formula, we have discussed the rules of changes of Boiling points of 1-Haloalkanes, calculated the boiling points of hydrogen molecule and hydrohalide molecules, compared the experimental values of the boiling points and finally discussed the meaning of the revised item briefly.