相转移催化合成O,O-二烷基(硫代)磷酰氯

Phase-Transfer-Catalyzed Preparation of Dialkylphorochoridotionate

以氢氧化钠的饱和溶液做缚酸剂 ,用三氯硫磷和相应的醇通过相转移催化反应合成 O,O-二烷氧基 (硫代 )磷酰氯 ,在温和条件下得较好收率。产物经 IR,1H NMR和 GC-MS表征。

WT5BZ]Dialkyl chorothiophosphates have been prepared in a good yield from thiophorylchloride and two equivalents of respective alcohol by a phase-transfer-catalyzed process in which sodium hydroxide saturated aqueous was used as acid accepter. The products were characterized by IR, 1H NMR and MS.