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马来酸酐和苯乙烯的可逆加成-断链链转移聚合及新型嵌段共聚物的合成 被引量:13

RADICAL REVERSE ADDITION-FRAGMENTATION CHAIN TRANSFER POLYMERIZATION OF MALEIC ANHYDRIDE WITH STYRENE AND A NOVEL FUNCTIONAL BLOCK COPOLYMER PREPARED THEREFROM
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摘要 Reverse addition\|fragmentation chain transfer (RAFT) polymerizatin of MAn with St is reported aiming at the synthesis of a well\|defined alternating copolymer of MAn with St.The results show that the polymers possess predetermined molecular weight and molecular weight distribution as narrow as 1 2. A novel well\|defined block copolymer P(MAn\| alt \|St)\| b \|PSt has also been prepared by the copolymerization of MAn with excess amount of St in molar feed via RAFT process. Reverse addition-fragmentation chain transfer (RAFT) polymerizatin of MAn with St is reported aiming at the synthesis of a well-defined alternating copolymer of MAn with St. The results show that the polymers possess predetermined molecular weight and molecular weight distribution as narrow as 1.2. A novel well-defined block copolymer P(MAn- alt-St)-b-PSt has also been prepared by the copolymerization of MAn with excess amount of St in molar feed via RAFT process.
出处 《高分子学报》 SCIE CAS CSCD 北大核心 2001年第3期415-417,共3页 Acta Polymerica Sinica
基金 国家自然科学基金资助项目 !(基金号 5 9773 0 18
关键词 可控聚合 可逆加成-断链链转移聚合 交替共聚合 嵌段共聚物 马来酸酐 苯乙烯 合成 controlled polymerization reverse addition-fragmentation chain transfer (RAFT) alternating copolymerization block copolymers
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参考文献4

  • 1Benoit D,Macromolecules,2000年,33卷,1505页
  • 2Chen G Q,Macromolecules,2000年,33卷,232页
  • 3Li F M,ACS Symp,2000年,384页
  • 4Wang J S,J Am Chem Soc,1995年,117卷,5614页

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