钙钛矿型稀土锰氧化物La_(0.7)Sr_(0.3)Fe_xMn_(1-x)O_3的磁性和巨磁电阻效应

Magnetic Properties and Colossal Magnetoresistance of La(Sr)MnO_3 Materials Doped with Fe

采用溶胶 凝胶工艺制备了La0 .7Sr0 .3FexMn1 -xO3化合物 ,研究Fe掺杂对材料的导电性能、磁性能、磁电阻性能的影响。发现随Fe含量的增加 ,材料的电阻率提高 ,铁磁居里温度 (TC)下降 ,巨磁电阻效应增强。观察到x =0 0 5和x =0 0 8的样品的电阻率随温度变化曲线出现双峰。对于x =0 0 8的样品 ,在室温附近磁电阻达到 18% (8× 10 5 A·m- 1 外场 )。对于x >0 0 8的样品 ,金属 绝缘体转变温度均比相应的铁磁 顺磁转变温度低 5 0～

La 0.7 Sr 0.3 Fe x Mn 1- x O 3 compounds (0 05≤ x ≤0 18) were prepared by the sol gel technique. The effect of Fe doping on the magnetic properties, conductivity and magnetoresistance for La 0.7 Sr 0.3 MnO 3 was investigated. Experimental results indicate that the Fe doping leads to a decrease in the ferromagnetic ordering temperature, an increase in the resistance and magnetoresistance effect. For samples of x =0 05 and x =0 08, two peaks are observed in their ρ T curve. MR of La 0.7 Sr 0.3 Fe 0.08 Mn 0.92 O 3 sample is 18% (8×10 5 A·m -1 , 293 K). At x ≥0 1, metal insulator (M I) transition temperature ( T p) is lower than ferromagnetic Curie temperature ( T C) by about 50～80 K.