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论液体导热机理与液体导热率方程 被引量:3

ON MECHANISM OF HEAT-CONDUCTION AND EQUATION OF THERMAL CONDUCTIVITY OF LIQUID
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摘要 文中根据作者建立的氩模型,从理论上阐明气体输运现象可用统一的数学方程描述,提出“气体不平衡状态方程”,进而将其移植应用于液体,提出液体导热率的半理论方程,经用极性与非极性等不同结构类型的液体纯质418个实验数据验证,平均误差1.7%,显著优于文献中各式。有重大的理论意义与实际应用价值。 According to the differential equation for a model of argon gas an equation for nonequiliblium state of gases was derived that could be extended to the liquid by which a thermal conductivity equation of normaal liquid was proposed as follows: λ_2=K_2[(T+140)/T^(14·7)]~n This equation can be applicd to both polar and nonpolar liquids. The average error from 418 experimental values is 1.7% based on 102 organic and inorganic compounds. It is far better than all other methods in published literature.
作者 张克武
机构地区 吉林柴油机厂
出处 《化学工程师》 CAS 1991年第3期4-7,共4页 Chemical Engineer
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同被引文献18

  • 1张宇英,张克武.论物质的分子结构与液体导热率理论方程[J].应用基础与工程科学学报,1999,7(2):149-157. 被引量:5
  • 2刘洪勤,汪文川,卢焕章.液体的导热系数与蒸发潜热及温度间的关系[J].化工学报,1993,44(1):41-48. 被引量:4
  • 3王克强.精确计算不同温度下液体导热系数的新方法[J].化学工程,1996,24(1):68-75. 被引量:5
  • 4张克武.有机分子的半金属结构理论模型与热力学性质──论有机纯质的微观结构与标准生成自由能[J].化工学报,1996,47(6):690-698. 被引量:16
  • 5Jeung H C, John C. A quantitative analysis of the thermai properties of porcine liver with glycerol at subzero and cryogenic temperatures [ J]. Cryobiology, 2008,57 : 79-83.
  • 6Jeung H C, John C. A quantitative analysis on the thermal properties of phosphate buffered saline with glycerol at subzero temperaturesI J]. In- ternational Journal of Heat and Mass Transfer,2008,51:640-649.
  • 7Towey J J, Dougan L. Structural examination of the impact of glycerol on water structure[ J]. Journal of Physical Chemistry ,2012,116 : 1633- 1641.
  • 8Nagoe A, Oguni M. Hydrogen-bond network formation of water mole- cules and its effects on the glass transitions in the ethylene glycol aque- ous solutions: failure of the Gordon-Taylor law in the water-rich range and absence of the T(g) = I15K rearrangement process in bulk pure water [ J ]. Journal of Physics-Condensed Matter, 2010,22 : 325103.
  • 9张克武.论液体内摩擦的机理与液体粘度方程[J]吉林化工学院学报,1988(03).
  • 10C. Baroncini,P. Filippo,G. Latini,M. Pacetti. Organic liquid thermal conductivity: A prediction method in the reduced temperature range 0.3 to 0.8[J] 1981,International Journal of Thermophysics(1):21~38

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