摘要
The relationships between stretching vibration frequencies (v) and distances (r) of the bonds Mo-S and Fe-Cl in ten compounds have been investigated- It is found that vMO-S is linearly related to rMo-s. This provides a convenient method to obtained bond distance data for some cluster compounds whose molecular structures could not be determined by X-ray analyses, The linear relationship between vFe-cl and rFe-cl is also discussed. The near-linear relationships of vvs. rFe-Mo and vFe-sb vs. rFe-Mo demons-trate that the formation of Fe-Sb bond has an important influence on the formation of Fe-Mo bond and the Fe-Mo distance may be estimated from v values.
The relationships between stretching vibration frequencies (v) and distances (r) of the bonds Mo-S and Fe-Cl in ten compounds have been investigated- It is found that vMO-S is linearly related to rMo-s. This provides a convenient method to obtained bond distance data for some cluster compounds whose molecular structures could not be determined by X-ray analyses, The linear relationship between vFe-cl and rFe-cl is also discussed. The near-linear relationships of vvs. rFe-Mo and vFe-sb vs. rFe-Mo demons-trate that the formation of Fe-Sb bond has an important influence on the formation of Fe-Mo bond and the Fe-Mo distance may be estimated from v values.
