CRYSTAL AND MOLECULAR STRUCTURE OF AuCSC(NH_2)_2]_2CiO_4 CONTAINING TWO-COORDINATE COMPLEX CATION

CRYSTAL AND MOLECULAR STRUCTURE OF AuCSC(NH_2)_2]_2CiO_4 CONTAINING TWO-COORDINATE COMPLEX CATION

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摘要 Au [SC(NH2)2]2C1O4, Mr,= 448. 66, orthorhombic, Pcca, α= 17. 873 (2),b = 8. 2933(7), c = 7. 196(2) A V=1066. 6A3,Z=4,DC = 2. 794g·cm-3,R= 0. 049,Rw=0. 068 for 807 observed reflections. The structure consists of complex cation Au[SC(NH2)2]2+ and perchlorate ion ClO4-. The gold atom( I ) in the cation has a slightly bent linear coordination geometry. Au [SC(NH2)2]2C1O4, Mr,= 448. 66, orthorhombic, Pcca, α= 17. 873 (2),b = 8. 2933(7), c = 7. 196(2) A V=1066. 6A3,Z=4,DC = 2. 794g·cm-3,R= 0. 049,Rw=0. 068 for 807 observed reflections. The structure consists of complex cation Au[SC(NH2)2]2+ and perchlorate ion ClO4-. The gold atom( I ) in the cation has a slightly bent linear coordination geometry.

作者林墀昌刘世雄等

出处《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 1990年第1期42-45,共4页 结构化学（英文）

分类号 O614.123 [理学—无机化学] O76 [理学—晶体学]

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1LIN Kun-Hua1,2 XIE Qing1 YANG Rui-Na1② XING Li-Ping1 JIN Dou-Man3 (1Henan Institute of Chemistry, Zhengzhou 450002, China) (2Zhengzhou University, Zhengzhou 450006, China) (3State Key Laboratory of Coordination Chemistry, Nanjing University 210093, Chin.Synthesis and Structure of the Copper(I) Complex Containing Bis(diphenylphosphino)ethane[J].Chinese Journal of Structural Chemistry,2002,21(1):51-54.
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Chinese Journal of Structural Chemistry

1990年第1期

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CRYSTAL AND MOLECULAR STRUCTURE OF AuCSC(NH_2)_2]_2CiO_4 CONTAINING TWO-COORDINATE COMPLEX CATION

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