摘要
C46H44N4O7PU, Mr = 1033. 89, monoclinic space group C2/c,a= 24. 110(3),b= 16. 879(2),c=27. 751(4) A ,B=96. 69(1),V= 11216. 5A3,Z=8, Dc=1.224 gcm-2, (MoKa) = 0. 71073A,u= 28.123cm-1,F(000) = 511, final R = 0. 052 for 3806 observable reflections. The uranyl ion UO|+ in the title complex forms a distorted pentagonal bipyramidal geometry with five oxygen atoms in the equatorial plane from two PMBP and one TBPO groups.
C46H44N4O7PU, Mr = 1033. 89, monoclinic space group C2/c,a= 24. 110(3),b= 16. 879(2),c=27. 751(4) A ,B=96. 69(1),V= 11216. 5A3,Z=8, Dc=1.224 gcm-2, (MoKa) = 0. 71073A,u= 28.123cm-1,F(000) = 511, final R = 0. 052 for 3806 observable reflections. The uranyl ion UO|+ in the title complex forms a distorted pentagonal bipyramidal geometry with five oxygen atoms in the equatorial plane from two PMBP and one TBPO groups.
