Xe(5p^56p)原子与氟利昂分子反应的产物研究

Studies on the Products for the Reactions of the Xe(5p^56p) Atoms with Freons

在双光子激发产生的Xe(2p_5),Xe(2p_6)态原子与CF_3Cl,CF_2Cl2,CF_2HCl以及CF_2ClBr分子的反应中,观察到了强的XeCl~*(B,C)产物荧光。测量了在200—380nm范围内的时间分辨光谱及产物生成速率常数。

The strong fluorescence from product XeCl* (B,C) was observed for the reactions of Xe(2p_5), Xe(2p_6) atoms with CF_3C1, CF_2C1_2, CF_2HC1 and CF_2ClBr. The time resolved spectra in 200-380 nm and the rate constants for XeCl(B,C) formation have been measured.