有机化合物的敏化光氧化反应

Sensitized Photooxygenation of organic compounds

本文着重阐述了有机化合物的电子转移敏化光氧化反应机理。作者根据大量实验事实将这种反应机理中繁杂的次级过程进行了系统的分类,并试图从结构与机理的关系上加以阐述,取得了较好的结果。相信这种观点对新反应体系的研究将产生较大影响。

The mechanisms of electron transfer sensitized photooxygenation of organic compounds were reviewed.The complicated mechanisms of secondary processes in this kind of organic photoreaction were syste-matically classified into five types,according to the relationship between structure and mechanism,and this classification was well suppnrted by many experimental facts reported in litaraturs.Such a classification must be valuble to the investigations of new photooxygenation systems.