金的化学进展和回顾

The advance and review of the chemistry of gold

本文回顾了七十年代后期到九十年代初金的化学科学的发展过程,阐述了金的类氢、类卤素和类碳性质。重点综述金化学的几个主要方面,包括Au^(-1)、Au~Ⅰ、Au~Ⅱ,Au~Ⅲ、Au~Ⅴ及金簇、金杂多金属簇化合物、金提取冶金化学等方面的某些重要成就。

The advance in gold chemistry from late 1970's to the early 1990's has been reviewed.The properties of pseudo-hydrogen,pseudo-halide and pseudo -carbonic of gold are discussed. Some significant achievements of several aspects of theoretical chemistry of gold including inorganic, organic compounds /complexes of Au-1, AuI, AuⅡ, AuⅢ, AuⅣ, AuⅤ as well as gold cluster, gold-heterometallic complexes, and metallurgical chemistry of gold extraction have been overviewed.