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气流粉碎对分子筛酸中心及催化性能的影响 被引量:1

Influence of Air Stream Pulverization on Molecular sieve Acid Center and Catalysis Ability
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摘要 用气流粉碎法将 Na ZSM- 5和 Na Y分子筛粉碎成微粉 ,作了粒度分布及比表面测定 ,根据吡啶吸附红外光谱分析其 B、L 酸中心的变化 ,粉碎后 HZSM- 5催化正己烷裂化和 HY催化正十六烷裂化的催化活性有显著增强 . The NaZSM 5 and NaY molecular sieve are pulverized by air stream to form fine particles The graininess distribution and specific surface area are determined The change of B and L acid centers is analysed based on IR absorption spectra Catalytic activities of hexane cracked by HZSM 5 and hexadecane cracked by HY are improved apparently
出处 《沈阳工业学院学报》 2001年第2期75-78,共4页 Journal of Shenyang Institute of Technology
关键词 气流粉碎 分子筛 裂化 酸中心 催化性能 air stream pulverization molecular sieve cracking
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参考文献3

  • 1Shitalkar V.P Joshi P N,Eapen M J.et al.Syntresis of ZSM-5 with variable crystallite size and its influence on physicochemical propetties[J].Zeolites.1991.11(5):511
  • 2Ramasamy P, Bahu G P, Chandwadkar A J, et al. Infuence of crystsl size of HZSM-5 on activity and shope selectivity in xylene isomerization[J], Zeolites, 1986, 6(2):98
  • 3Corma A, Wejclechowski B W. The chemistry of catalytic cracking[J]. Catalysis Revolution Science Englneering. 1985, 27(1):29.

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