摘要
合成了 2种新型的二环乙酮草酰二腙 (BCO)桥联的双核铜 (Ⅱ )配合物 [Cu2 (BCO) (ClO4 ) 2 L2 ](ClO4 ) 2 ,其中L代表 1,10_邻菲咯啉 (phen)和 5_硝基_1,10_邻菲咯啉 (NO2 phen) .经元素分析、摩尔电导以及红外光谱和电子光谱等方法对这些配合物进行了表征 ,推定了配合物的组成和结构 ,并用循环伏安法研究了配合物 [Cu2 (BCO) (ClO4 ) 2 (phen) 2 ](ClO4 ) 2 (1)的电化学性质 .
Two novel binuclear copper(Ⅱ)complexes were synthesized and bridged by Biscyclohexanone Oxalyldihydrazone. phen and NO 2phen denotes 1,10-phenanthroline and 5-nitro-1,10-phenanthroline respectively. The complexes have been characterized by elemental analyses, nolar conductance, IR and electronic spectra. Their structures were proposed and the electrochemical property of the complex (1) has been investigated with cyclic voltammetry.
出处
《曲阜师范大学学报（自然科学版）》
CAS
2001年第3期71-73,共3页
Journal of Qufu Normal University(Natural Science)
关键词
二环己酮草酰二腙
合成
电化学性质
双核铜配合物
binuclear copper(Ⅱ)complexes
Biscyclohexanone Oxalyldihydrazone
synthesis
electrochemical property
